Papers by Dr. Benlih Huang
by Dr. Ning-Cheng Lee , Dr. Hong-Sik Hwang, Dr. Benlih Huang
Addition of Al into SAC alloys reduces the number of hard Ag3Sn and Cu6Sn5 IMC particles, and forms larger, softer non-stoichiometric AlAg and AlCu particles. This results in a significant reduction in yield strength, and also causes some moderate increase in creep rate. For high Ag SAC alloys, adding Al 0.1-0.6% to SAC alloys is most effective in softening, and brings the yield strength down to the level of SAC105 and SAC1505, while the creep rate is still maintained at SAC305 level. Addition of Ni results in formation of large (Ni,Cu)3Sn4 IMC particles and loss of Cu6Sn5 particles. This also causes softening of SAC alloys, although to a less extent than that of Al addition. Addition of Al also drives the microstructure to shift from near-ternary SnAgCu eutectic toward combination of eutectic SnAg and eutectic SnCu. Addition of Ni drives shifting toward eutectic SnAg. For SAC+Al+Ni alloys, the pasty range and liquidus temperature are about 4°C less than that of SAC105 or SAC1505 if the addition quantity is less than about 0.6%. Addition of Al and Ni also results in a slight decrease in modulus and elongation at break, although the tensile strength is not affected.
Ni, Al, creep resistant, compliant, soften, SAC, lead-free, solder
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Posted on 1 Jan 2009
by Dr. Ning-Cheng Lee , Dr. Benlih Huang, William Manning, Dr. Yan Liu
Voiding is attributed to the flux outgassing within the solder joints when the solder is at molten state. The effect of reflow profile on voiding at microvia for lead-free soldering is strongly dependent on the flux chemistry. In general, wetting is more important than
melting outgasing behavior, and can be enhanced by employing a higher melting energy, including both higher peak temperature and longer dwell time. Use of a high soaking energy can help drying out volatiles hence reduce the melting outgasing and result in low
voiding, but may also increase oxidation for pastes with poor oxidation resistance and cause a high voiding. Testing oxidation resistance of solder paste beforehand will promise a more accurate selection of soaking energy.
pb-free, soldering, BGA, CSP, void, voiding, SMT, solder, lead-free, microvia, profile, reflow
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Posted on 2 Mar 2010
by Dr. Benlih Huang, Dr. Ning-Cheng Lee
Tombstoning of SnAgCu is affected by the solder composition. At vapor phase soldering, both wetting force and wetting time at a temperature well above the melting point have no correlation with the tombstoning behavior. Since tombstoning is caused by unbalanced wetting force, the results suggest that the tombstoning maybe dictated by the wetting at the onset of paste melting stage. A maximal tombstoning rate is observed at 95.5Sn3.5Ag1Cu. The tombstoning rate decreases with increasing deviation in Ag content from this composition. DSC study indicates that this is mainly due to the increasing presence of pasty phase in the solders, which is expected to result in a slower wetting speed at the onset of solder paste melting stage. Surface tension plays a minor role, with lower surface tension correlates with a higher tombstoning rate. SnAgCu composition with a Ag content lower than 3.5%, such as 2.5Ag, is more favorable in terms of reducing tombstoning rate with minimal risk of forming AgSn intermetallic platelet.
pb-free, tombstoning, solder, soldering, solder paste, flux, lead-free, surface mount
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Posted on 4 Mar 2010
by Dr. Arnab Dasgupta, Dr. Benlih Huang, Dr. Ning-Cheng Lee
For SnAgCu solder, the voiding rate at microvia was studied with the use of simulated microvia, and was the lowest with 95.5Sn3.8Ag0.7Cu and 95.5Sn3.5Ag1Cu, and increased with further decrease in Ag content. Results indicated that voiding at microvia was governed by via filling and exclusion of fluxes. The voiding rate decreased with decreasing surface tension and increasing wetting force which in turn was dictated by the solder wetting or spreading. Both low surface tension and high solder wetting prevented the flux from being entrapped within microvia. A fast wetting speed might also facilitate reducing voiding. However, this factor was considered not as important as the final solder coverage area.
pb-free, reflow, surface mount, microvia, voiding, void, lead-free, soldering, solder
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Posted on 4 Mar 2010
by Dr. Benlih Huang, Dr. Ning-Cheng Lee
Tombstoning has plagued the surface mount assembly industry for decades. While the problem seemed under control, it has begun creeping in again due to the miniaturization of discretes such as 0402S and 0201S. This article studies tombstoning behavior on a series of SN AG CU Lead-Free Solders and attempts to find a way to control the problem.
lead-free, pb-free, tombstoning, solder, solder paste, SMT, solder alloy, pasty range, soldering, reflow
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Posted on 1 Jan 2009
by Dr. Ning-Cheng Lee , Dr. Benlih Huang
The prospects of 10 major lead-free solder alloys for being widely used for reflow soldering are studied in this work. Compatibility of those alloys with a variety of representative flux chemistries is considered essential, and is determined for performance in handling- ability, including shelf life and tack time, and soldering capability, including solder balling, wetting, and solder joint appearance. Results indicate that the control 63Sn37Pb is still the most compatible alloy, rated 27.1 in compatibility out of a full scale 30 when using warm profile. The primary factor which distinguishes 63Sn37Pb from the rest alloys is the soldering performance, particularly the wetting and solder appearance. As to the solder balling, although 63Sn37Pb is also the best, it is fairly close to the best lead-free systems. Among the lead-free options, both SnAgBi alloys studied here, 91.7Sn3.5Ag4.8Bi and 90.5Sn7.5Bi2Ag, turn out to be on the top of lead-free systems, rated 22.9 and 22.8, respectively. This is mainly attributed to the better wetting and solder balling performance. Shelf life and tack time of the SnAgBi systems are also fairly good, while the solder appearance is at best considered average. The six alloys, 99.3Sn0.7Cu, 95.5Sn3.8Ag0.7Cu, 93.6Sn4.7Ag1.7Cu, 96.2Sn2.5Ag0.8Cu0.5Sb, 58Bi42Sn, and 95Sn5Sb, show fairly comparable performance to each other, with compatibility ranging from 19.3 to 20.3. In general, the whole group displays a quite noticeably poorer wetting than SnAgBi systems. 58Bi42Sn exhibits a fairly poor solder balling performance, but an outstanding solder appearance among lead-free systems. 96.2Sn2.5Ag0.8Cu0.5Sb shows a relatively poor performance in both wetting and solder appearance among these six alloys. 96.5Sn3.5Ag, rated 17.1 in compatibility, is ranked below the other alloys described above, mainly due to poor performance in solder balling, and particularly the poor wetting. 89Sn8Zn3Bi, rated only 2.2 in compatibility, falls far short in every category when compared with all other alloy systems. Obviously, this is attributable to the very reactive nature of zinc, which results in excessive oxidation of metal and excessive reaction with fluxes, and consequently a definitely unacceptable performance for solder paste applications. High-tin-content lead-free alloys seem to display a thicker IMC layer than eutectic SnPb when reflowed.
pb-free, tack time, shelf life, solder appearance, solder balling, wetting, flux, paste, reflow, soldering, solder, lead-free
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Posted on 1 Jan 2009
by Dr. Benlih Huang, Dr. Ning-Cheng Lee
Several unique solder paste systems have been developed and tested for 63Sn/37Pb solder bumping for wafer, CSP, and BGA with the low cost print-detach-reflow process. The results indicate that the bump height achieved is very adequate and consistent for all three area array package systems. Microstructure of solder bumps appears normal. The yield is also very high for both before reflow and after reflow condition, and is dictated by printing performance. With the unique high slump resistance exhibited by those newly developed pastes, the paste transfer efficiency at printing stage becomes the most critical performance for this process. The transfer efficiency increases with increasing area ratio, increasing taper angle, decreasing pitch, decreasing stencil thickness, decreasing challenge, with adoption of square aperture design, and is not sensitive to aspect ratio of aperture to solder particle size. The paste systems appear to have more potential for depositing a larger amount of paste per unit pitch, as evidenced by the linear relation between expected paste volume and the deposited paste volume. Increasing metal content helps improving bumping performance. The bottleneck of increasing bumping performance for wafer applications appears to be developing a stencil manufacturing technology capable of providing an aperture pattern with spacing considerably smaller than the stencil thickness. Slow print speed is also essential for adequate printing. A non-shiny non-smooth stencil surface is considered beneficial for aiding paste rolling. The flux residue of those pastes is cleanable with solvents.
solder, soldering, area array package, Flip Chip, BGA, CSP, sphere, Bumping, paste, flux, fluxless, pb-free, lead-free
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Posted on 1 Jan 2009
