Papers about reflow
by Dr. Ning-Cheng Lee , Iris Artaki, James Slattery, John R. Sovinsky, Paul T. Vianco
Environmental and toxicity concerns related to the use of lead have initiated the search for acceptable, alternate joining materials for electronics assembly. This paper describes a novel
lead-free solder designed as a "drop in" replacement for common tin/lead eutectic solder. The physical and mechanical properties of this solder are discussed in detail with comparison to tin/lead eutectic solder. The performance of this solder when used for electronics assembly is discussed and compared to other common solders. Fatigue testing results are reported for thermal cycling electronics assemblies soldered with this lead-free composition. The paper concludes with a discussion on indium metal availability, supply and price.
pb-free, surface mount, SMT, solder paste, reflow, electronic, lead-free, soldering, solder
[Permanent Link to this Paper ]
Posted on 1 Jan 2009
by Paul A. Jaeger, Dr. Ning-Cheng Lee
As one of the major approaches to address the CFC issue, no-clean solder paste has received rapidly increasing attention. Although currently the industry seems to accept full residue paste as a temporary solution, the low residue no-clean paste technology using inert or reactive atmosphere advances immensely to meet the challenge. Presently consensus has not been established yet regarding how low a residue level could be achieved and how inert the atmospheres needs to be. In this study, a semi-empirical model is proposed to predict the soldering performance of low residue solder pastes under various levels of inert reflow atmosphere. The model predicts that the soldering performance would improve rapidly then gradually level off with decreasing oxygen content. The soldering performance vs oxygen content curves are superimposable, with the lower residue one leveling off at lower oxygen level. In general, the experimental data match this model fairly well. However, the data also indicate that, although inert atmosphere improves soldering performance, the optimum condition for bond strength performance seems to demand the presence of some oxygen. This unexpected behavior suggests that a very tight low oxygen level control may not be required. The mechanism responsible for this phenomenon can be attributed to oxidation-induced resin crosslinking. This slows down the flux drying rate as well as hinders the permeation of oxygen through the flux layer.
lead-free, pb-free, nitrogen, flux, reflow, soldering, low-residue, no-clean, solder paste, solder
[Permanent Link to this Paper ]
Posted on 1 Jan 2009
by Dr. Ning-Cheng Lee , Dr. Benlih Huang, William Manning, Dr. Yan Liu
Voiding is attributed to the flux outgassing within the solder joints when the solder is at molten state. The effect of reflow profile on voiding at microvia for lead-free soldering is strongly dependent on the flux chemistry. In general, wetting is more important than
melting outgasing behavior, and can be enhanced by employing a higher melting energy, including both higher peak temperature and longer dwell time. Use of a high soaking energy can help drying out volatiles hence reduce the melting outgasing and result in low
voiding, but may also increase oxidation for pastes with poor oxidation resistance and cause a high voiding. Testing oxidation resistance of solder paste beforehand will promise a more accurate selection of soaking energy.
pb-free, soldering, BGA, CSP, void, voiding, SMT, solder, lead-free, microvia, profile, reflow
[Permanent Link to this Paper ]
Posted on 2 Mar 2010
by Timothy Jensen , Dr. Ronald C. Lasky
Chinese version of Challenges of Implementing a
Halogen-Free PCB Assembly Process.
oxidation barrier, activator, pb-free, reflow, graping, head-in-pillow, halide-free, halogen-free, halogens, CHINESE LANGUAGE
[Permanent Link to this Paper ]
Posted on 22 Mar 2010
by Dr. Ronald C. Lasky , Timothy Jensen
The electronics industry continues to strive to provide more environmentally friendly products. This movement is partly due to legislation from various countries, partly due to public outcry from well publicized 3rd world recycling practices, and partly due to non-government organizations (NGOs) testing and publishing information on electronic devices regarding their content of various toxic materials. One set of materials targeted for reduction and eventual elimination are halogenated compounds. Halogens are found in plastics for cables and housings, board laminate materials, components, and soldering fluxes. Replacing these halogenated compounds can have a dramatic affect on the PCB
assembly process. In this paper those challenges will be discussed as well as techniques and practices that will help ensure high end of line yields and continued reliability.
oxidation barrier, activator, pb-free, reflow, graping, head-in-pillow, halide-free, halogen-free, halogens
[Permanent Link to this Paper ]
Posted on 4 Mar 2010
by Andy C. Mackie PhD
In my twenty years in the electronics manufacturing industry, I have heard a lot of claims made about the use of nitrogen in inerted soldering processes: many of them completely wrong.
In this paper, we will talk about reflow in an enclosed oven, although many of these discussions may pertain to wave soldering and even vacuum soldering.
electronics manufacturing, reflow, soldering
[Permanent Link to this Paper ]
Posted on 24 Jan 2011
by Dr. Arnab Dasgupta, Dr. Benlih Huang, Dr. Ning-Cheng Lee
For SnAgCu solder, the voiding rate at microvia was studied with the use of simulated microvia, and was the lowest with 95.5Sn3.8Ag0.7Cu and 95.5Sn3.5Ag1Cu, and increased with further decrease in Ag content. Results indicated that voiding at microvia was governed by via filling and exclusion of fluxes. The voiding rate decreased with decreasing surface tension and increasing wetting force which in turn was dictated by the solder wetting or spreading. Both low surface tension and high solder wetting prevented the flux from being entrapped within microvia. A fast wetting speed might also facilitate reducing voiding. However, this factor was considered not as important as the final solder coverage area.
pb-free, reflow, surface mount, microvia, voiding, void, lead-free, soldering, solder
[Permanent Link to this Paper ]
Posted on 4 Mar 2010
by Dr. Benlih Huang, Dr. Ning-Cheng Lee
Tombstoning has plagued the surface mount assembly industry for decades. While the problem seemed under control, it has begun creeping in again due to the miniaturization of discretes such as 0402S and 0201S. This article studies tombstoning behavior on a series of SN AG CU Lead-Free Solders and attempts to find a way to control the problem.
lead-free, pb-free, tombstoning, solder, solder paste, SMT, solder alloy, pasty range, soldering, reflow
[Permanent Link to this Paper ]
Posted on 1 Jan 2009
by Dr. Ning-Cheng Lee
The reflow profile is engineered to optimize the soldering performance based on defect mechanisms analysis. In general, a slow ramp-up rate is desired in order to minimize hot slump, bridging, tombstoning, skewing, wicking, opens, solder beading, solder balling, and components cracking. A minimized soaking zone reduces voiding, poor wetting, solder balling, and opens. Use of low peak temperature lessens charring, delamination, intermetallics, leaching, dewetting, and voiding. A rapid cooling rate helps reducing intermetallics, charring, leaching, dewetting, and grain size. However, a slow cooling rate reduces solder or pad detachment. The optimized profile favors that the temperature ramps up slowly until reaching about 180°C. The temperature is then gradually raised further up to 186°C within about 30 seconds, then raised rapidly until reaching about 220°C. After that, the temperature is brought down with a rapid cooling rate. The conventional profile was developed due to the limitation of past reflow technologies. Implementation of the optimized profile requires the support of a heating-efficient reflow technology with a controllable heating rate. Vapor phase reflow can provide a rapid heating, but has difficulty to control the heating rate. Infrared reflow can regulate the heating rate, but is sensitive to variation in parts features. Emergence of the forced air convection reflow provides controllable heating rate. In addition, it is not sensitive to variation in parts
features, thus allows the realization of the optimized profile.
lead-free, pb-free, SMT, vapor phase, infrared, convection, soldering, solder paste, flux, defect, profile, reflow
[Permanent Link to this Paper ]
Posted on 1 Jan 2009
by Dr. Ning-Cheng Lee , Dr. Benlih Huang
The prospects of 10 major lead-free solder alloys for being widely used for reflow soldering are studied in this work. Compatibility of those alloys with a variety of representative flux chemistries is considered essential, and is determined for performance in handling- ability, including shelf life and tack time, and soldering capability, including solder balling, wetting, and solder joint appearance. Results indicate that the control 63Sn37Pb is still the most compatible alloy, rated 27.1 in compatibility out of a full scale 30 when using warm profile. The primary factor which distinguishes 63Sn37Pb from the rest alloys is the soldering performance, particularly the wetting and solder appearance. As to the solder balling, although 63Sn37Pb is also the best, it is fairly close to the best lead-free systems. Among the lead-free options, both SnAgBi alloys studied here, 91.7Sn3.5Ag4.8Bi and 90.5Sn7.5Bi2Ag, turn out to be on the top of lead-free systems, rated 22.9 and 22.8, respectively. This is mainly attributed to the better wetting and solder balling performance. Shelf life and tack time of the SnAgBi systems are also fairly good, while the solder appearance is at best considered average. The six alloys, 99.3Sn0.7Cu, 95.5Sn3.8Ag0.7Cu, 93.6Sn4.7Ag1.7Cu, 96.2Sn2.5Ag0.8Cu0.5Sb, 58Bi42Sn, and 95Sn5Sb, show fairly comparable performance to each other, with compatibility ranging from 19.3 to 20.3. In general, the whole group displays a quite noticeably poorer wetting than SnAgBi systems. 58Bi42Sn exhibits a fairly poor solder balling performance, but an outstanding solder appearance among lead-free systems. 96.2Sn2.5Ag0.8Cu0.5Sb shows a relatively poor performance in both wetting and solder appearance among these six alloys. 96.5Sn3.5Ag, rated 17.1 in compatibility, is ranked below the other alloys described above, mainly due to poor performance in solder balling, and particularly the poor wetting. 89Sn8Zn3Bi, rated only 2.2 in compatibility, falls far short in every category when compared with all other alloy systems. Obviously, this is attributable to the very reactive nature of zinc, which results in excessive oxidation of metal and excessive reaction with fluxes, and consequently a definitely unacceptable performance for solder paste applications. High-tin-content lead-free alloys seem to display a thicker IMC layer than eutectic SnPb when reflowed.
pb-free, tack time, shelf life, solder appearance, solder balling, wetting, flux, paste, reflow, soldering, solder, lead-free
[Permanent Link to this Paper ]
Posted on 1 Jan 2009
by Dr. Ning-Cheng Lee
Reflow soldering of solder paste is the primary interconnection method used in SMT assembly process. The major issues which plague the reflow soldering performance include, but not limited to, bottom-side-component-holding, bridging, dewetting, low-residue, opening, solder balling, solder beading, solder-fillet-lifting, tombstoning, defective balling for BGA, and voiding. The mechanisms, causes, and cures for each issue are briefly discussed in this article.
lead-free, soldering, solder paste, SMT, bridging, dewetting, opening, solder balling, solder beading, solder-fillet-lifting, tombstoning, balling for BGA, voiding, pb-free, reflow
[Permanent Link to this Paper ]
Posted on 1 Jan 2009
by Timothy Jensen
As the July 1, 2006 Pb-free deadline approaches, many electronics assemblers are beginning to fathom the changes and process demands required. The two biggest material concerns involve solder paste and components. This document provides practical recommendations for evaluating Pb-free solder pastes and ensuring that the selected solder paste will deliver assembly yields comparable to, or better than, the incumbent Sn/Pb solder paste.
lead-free, pb-free, stencil printing, reflow, response to pause, evaluation, solder paste
[Permanent Link to this Paper ]
Posted on 1 Jan 2009
by Dr. Ning-Cheng Lee , Dr. Yan Liu, Pamela Fiacco
Head-in-pillow (HIP) is ailing the electronic industry when assembling BGAs or CSPs onto PCBs. It is caused by warpage of components or boards at reflow process, and is aggravated by oxidation. Methods for assessing the potential for occurrence of HIP are highly desired by the industry. Besides using BGA rework station followed by tedious dye and pry treatment, two other simpler methods are introduced in this work, Tiny Dot Paste method and Ball Onto Paste method. The Tiny Dot Paste method is stressed on the assessment of oxidation barrier capability of solder paste, while Ball Onto Paste method assesses combined capability of oxidation resistance and excessive fluxing capacity. Both methods are quick, easy, and close simulation, with the latter being better in real process simulation. Prevention of HIP can be accomplished by (1) designing packages without warpage, (2) printing more paste, (3) dipping solder paste or flux, (4) using inert reflow atmosphere, (5) reducing reflow temperature, (6) placing heat shield on BGA or CSP, (7) avoiding using water soluble solder paste for BGA bumped with no-clean process, (8) using solder bumps or solder powder with oxidation resistant alloy, (9) using fluxes with high oxidation barrier capability and high fluxing capacity. Among all options listed above, using solder paste with high oxidation barrier capability and high fluxing capacity is considered the most easily implemented approaches.
head-in-pillow, solder, soldering, reflow, SMT, solder paste, BGA, CSP
[Permanent Link to this Paper ]
Posted on 24 Jan 2011
by Dr. Ning-Cheng Lee , Dr. Yan Liu, Derrick Herron
Quad Flat No Leads (QFN) package designs receive more and more attention in electronic industry nowadays. This package offers a number of benefits including (1) small size, such as a near die-sized footprint, thin profile, and light weight; (2) easy PCB trace routing due to the use of perimeter I/O pads; (3) reduced lead inductance; (4) easy PCB trace routing; and (5) good thermal and electrical performance due to the adoption of exposed copper die-pad technology. These features make the QFN an ideal choice for many new applications where size, weight, electrical, and thermal properties are important. However, adoption of QFN often runs into voiding issues at SMT assembly. Upon reflow, outgassing of solder paste flux at the large thermal pad has difficulty escaping and inevitably results in voiding. It is well known that the presence of voids will affect the mechanical properties of joints and deteriorate the strength, ductility, creep, and fatigue life. In addition, voids could also produce spot overheating, lessening the reliability of the joints. This is particularly a concern for QFN where the primary function of thermal pads is for heat dissipation. Thermal pad voiding control at QFN assembly is a major challenge due to the large coverage area, large number of via, and low standoff. Both design and process were studied for minimizing and controlling the voiding. Eliminating the via by plugging is most effective in reducing the voiding. For an open via situation, a full thermal pad is desired for a low number of via. For a large number of via, a divided thermal pad is preferred due to better venting capability. Placement of a via at the perimeter prevents voiding caused by via. A wider venting channel has a negligible effect on voiding and reduces joint continuity. For divided thermal pada, the SMD system is more favorable than the NSMD system, with the latter suffering more voiding due to a thinner solder joint and possibly board outgassing. Performance of a divided thermal pad is dictated by venting accessibility, not by the shape. Voiding reduction increases with increasing venting accessibility, although introduction of a channel area compromises the continuity of solder joint. Reduced solder paste volume causes more voiding. Short profiles and long hot profiles are most promising in reducing the voiding. Voiding behavior of a QFN is similar to typical SMT voiding and increases with pad oxidation and further reflow.
solder paste, reflow, SMT, solder, void
[Permanent Link to this Paper ]
Posted on 21 Feb 2011
by Wanda B. Hance, Dr. Ning-Cheng Lee
The mechanisms for void formation are investigated for applications involving solder paste in SMT. Generally the voids are caused by the outgassing of entrapped flux in the sandwiched solder during reflow. The voiding is mainly dictated by the solderability of metallization, and increases with decreasing solderability of metallization, decreasing flux activity, increasing metal load of powder, and increasing coverage area under the lead of the joint. Decrease in the solder powder particle size shows only a slightly negative effect toward voiding. The data indicate that voiding is also a function of the timing between the coalescing of solder powder and the elimination of immobile metallization oxide. The sooner the paste coalescing occurs, the worse the voiding will be. Increase in voiding usually is accompanied by an increasing fraction of large voids, suggesting factors causing voiding will have an even greater impact on the joint reliability than what shown by the total-void-volume analysis results. Preliminary data show that certain predry treatment and flux solvent with higher boiling point appear to cause increased voiding.
lead-free, pb-free, solderability, reflow, solder joint, SMT, voiding, void, flux, solder paste, soldering, solder
[Permanent Link to this Paper ]
Posted on 1 Jan 2009
