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High Melting Pb-free Solder Paste

Dr Ning-Cheng Lee (Indium Corporation's Vice-President of Technology) just let me review his team's excellent upcoming paper on solder technology for high temperature Pb-free (lead-free) [HTLF] applications, such as Power Semiconductor die-attach. Dr Lee will be giving this paper at the ICEPT-HDP Conference in Shanghai (August 2011).

The basis of his work is that solders that do not melt at 260C ( that is, solidus > 260C), and thus are theoretically able to allow components to pass MSL level 1 testing per JEDEC/IPC J-STD-020D-.01, usually have a variety of drawbacks. These include cost, sensitivity to oxidation, poor wetting, and excessively high required reflow temperatures. For some engineers, gold/tin (the eutectic 80Au/20Sn alloy or 79Au/21Sn) with its high melting point (eutectic m.p = 280C) and excellent thermal conductivity remains the only possible solution, but the rising cost of gold is driving many to seek viable alternatives.

Dr Lee's team's innovation is a mixed-solder approach called BiAgX®, which uses one of the solder components to melt and form an intermetallic with the substrate surface, which is then itself wetted by the majority alloy component of the paste.

The most dramatic evidence of BiAgX®'s improvement in wetting/solderability over the standard 89%Bi/11%Ag alloy is seen in photographs (right) of reflow onto oxidized bare copper and alloy 42.

There are also dramatic improvements in thermal cycling over the standard Indalloy 151 (92.5Pb/5Sn/2.5Ag) and 171 (95Pb/5Sn), too, and I look forward to discussing this further with the team. I recommend you watch Dr Lee's presentation or read his paper to learn more.

Please note, as always, that the metal percentages reported in the above are all based on weight (%w/w), not on molar units.

Cheers!  Andy